The nitration of piperonal

JB Ekeley, MS Klemme

Index: Ekeley; Klemme Journal of the American Chemical Society, 1928 , vol. 50, p. 2713

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Citation Number: 13

Abstract

Theory of Modification The authors believe and experiments indicate that the violence of the ordinary Skraup reaction is due to the sudden liberation of acrolein result- ing from the action of sulfuric acid upon the glycerol. The acetic acid was introduced in an effort to form a glycerol mono or diacetate and thereby remove a large proportion of the glycerol from the reaction sphere. Acetic acid was used because it is quite stable and relatively cheap.