N??Isopropyl enols of carboxylic acid amides

…, D Casarini, G Cerioni, Z Rappoport

Index: Lei, Yi Xiong; Casarini, Daniele; Cerioni, Giovanni; Rappoport, Zvi Journal of Organic Chemistry, 2003 , vol. 68, # 3 p. 947 - 959

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Citation Number: 18

Abstract

Abstract Eight N-isopropyl compounds of the formal structure YY′ CHCONHPr-i (6), Y, Y′= CO 2 Me, CO 2 CH 2 CF 3, CN; YY′= Meldrum′ s acid residue; Y= CO 2 Me, Y′= CO 2 CH 2 CF 3, CN; Y= CO 2 CH 2 CF 3, CO 2 CH (CF 3) 2, Y′= CN, and the Nt-butyl derivative of Meldrum's acid were prepared and their structures were investigated in the solid state and in solution. The x-ray diffraction data indicate that in the solid state the structure is that of ...