Journal of the American Chemical Society

α-Halosulfones. IV. A Facile Conversion of Mercaptans to Homologous Terminal Olefins

LA Paquette

Index: Paquette,L.A. Journal of the American Chemical Society, 1964 , vol. 86, p. 4383 - 4385

Full Text: HTML

Citation Number: 1

Abstract

Discussion Examples of reactions which reach equilibrium are rare in organic chemistry, and kinetic considerations are usually more useful than thermodynamics in predicting reaction products, particularly at the temperatures at which most carbon chemistry is studied (-100 to+ 200), Notable exceptions are the rearrangements of various groups on the benzene nucleus" and scrambling of atoms other than carbon on carbon atoms. 12 ...