Isoreticular chiral metal− organic frameworks for asymmetric alkene epoxidation: tuning catalytic activity by controlling framework catenation and varying open channel …

F Song, C Wang, JM Falkowski, L Ma…

Index: Song, Feijie; Wang, Cheng; Falkowski, Joseph M.; Ma, Liqing; Lin, Wenbin Journal of the American Chemical Society, 2010 , vol. 132, # 43 p. 15390 - 15398

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Citation Number: 409

Abstract

A family of isoreticular chiral metal− organic frameworks (CMOFs) of the primitive cubic network topology was constructed from [Zn4 (μ4-O)(O2CR) 6] secondary building units and systematically elongated dicarboxylate struts that are derived from chiral Mn-Salen catalytic subunits. CMOFs 1− 5 were synthesized by directly incorporating three different chiral Mn- Salen struts into the frameworks under solvothermal conditions, and they were ...