Immobilization of ruthenium catalysts for allylations with allyl alcohol

JA van Rijn, E Bouwman, E Drent

Index: Van Rijn, Jimmy A.; Bouwman, Elisabeth; Drent, Eite Journal of Molecular Catalysis A: Chemical, 2010 , vol. 330, # 1-2 p. 26 - 34

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Citation Number: 3

Abstract

[RuCp (PP)]+ complexes active for allylation of alcohols with allyl alcohol as the allylating agent were immobilized on solid supports. Two different immobilization methods have been applied:(1) via electrostatic interactions of the cationic complex on ion-exchange resins, where the anion is present on the support and (2) via a coordination bond with a ligand covalently-bound on the support. Both methods give high yields of immobilized complex ...