Experimental and theoretical study of the F, Cl and Br reactions with formaldehyde and acetaldehyde

JA Beukes, B D'Anna, V Bakken…

Index: Nielsen; Beukes; D'Anna; Bakken Physical Chemistry Chemical Physics, 2000 , vol. 2, # 18 p. 4049 - 4060

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Citation Number: 39

Abstract

The vapour phase reactions of formaldehyde, formaldehyde-d2, 13C-formaldehyde, acetaldehyde, acetaldehyde-1-d1, acetaldehyde-2, 2, 2-d3, and acetaldehyde-d4 with Cl and Br atoms were studied at 298±2 K and 1013±10 hPa using long-path FTIR detection. For formaldehyde the only products observed were HCl, HBr and CO; for acetaldehyde the product distribution suggests one dominant channel: CH3CHO+ X→ CH3CO+ HX. The ...

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