Abnormal products in the Siegrist reaction involving ortho-fluorinated intermediates

MS Newman, B Dhawan, S Kumar

Index: Newman,M.S. et al. Journal of Organic Chemistry, 1978 , vol. 43, p. 524 - 525

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Citation Number: 4

Abstract

The syntheses of trans-1-(1 fluoro-2-naphthyl)-2-phenyl-ethylene (1) and trans-1-(1-fluoro-2- naphthyl)-24 o-iodopheny1) ethylene (2) via the Wittig reaction as intermediates for the attempted photochemical synthesis of 7-fluorobenz [a] anthracene (3) have been de~ cribed.~ Unfortunately, insufficient 3 was made (only via 2 as use of 1 failed) for adequate testing for possible carcinogenic activity. Because of our interest in preparing larger ...