Inorganic Chemistry

Electron-transfer reactions of manganese (II) and-(III) polyamino carboxylate complexes in aqueous media

DH Macartney, DW Thompson

Index: Macartney, Donal H.; Thompson, David W. Inorganic Chemistry, 1989 , vol. 28, p. 2195 - 2199

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Citation Number: 22

Abstract

The kinetics of electron-transfer reactions involving the manganese (I1) and-(III) complexes of ethylenediaminetetraacetate (edtac) and trans-l, 2-~ yclohexanediaminetetraacetate (cdta4-) have been investigated in aqueous media. The cross-reactants employed in this study are osmium and cobalt tris (po1ypyridine) complexes, IrC16>, and nickel polyaza complexes. The cross-reaction kinetic data have been correlated in terms of the Marcus ...