Journal of the American Chemical Society

Diels-Alder reactions of Fischer carbene complexes

WD Wulff, DC Yang

Index: Wulff, William D.; Yang, Dominic C. Journal of the American Chemical Society, 1983 , vol. 105, # 22 p. 6726 - 6727

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Citation Number: 91

Abstract

The heteroatom-stabilized carbene complexes of the group 6 transition metals (Fischer carbene Complexes') were the first to be prepared2 and are among the most stable of all transition-metal carbene c~ mplexes.~ The chemical and physical properties of these complexes have been interpreted in terms of a polarized chromium-carbon bond with the carbon bearing an appreciable positive~ harge.~ J An example is the tremendous ...