Structure determination of bitter principles in Ailanthus altissima. Structure of shinjulactone A and revised structure of ailanthone

H Naora, M Ishibashi, T Furuno, T Tsuyuki…

Index: Naora, Hirokazu; Ishibashi, Masami; Furuno, Tetsuo; Tsuyuki, Takahiko; Murae, Tatsushi; et al. Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 12 p. 3694 - 3698

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Citation Number: 36

Abstract

The structure of a new bitter principle, shinjulactone A, isolated from Ailanthus altissima SWINGLE was determined to be 11β, 20-epoxy-1β, 2α, 11α, 12α-tetrahydroxypicrasa-3, 13 (21)-dien-16-one and the configuration of a hydroxyl group at C-12 of ailanthone was revised to α-orientation by X-ray analysis.