Polyhedron

Synthesis and X-ray crystal structure of derivatives from the N, N-bis (1H-pyrazolyl-1-methyl) aniline (dichloro) Zn (II) complex: Substituent effects on the phenyl ring …

E Kim, HY Woo, S Kim, H Lee, D Kim, H Lee

Index: Lee, Hyosun; Kim, Eunhee; Woo, Hyun Yul; Kim, Sunghoon; Lee, Hajin; Kim, Dongil Polyhedron, 2012 , vol. 42, # 1 p. 135 - 141

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Citation Number: 16

Abstract

The reaction of anhydrous ZnCl2 with ancillary ligands, including N, N-bis (1H-pyrazolyl-1- methyl) aniline (L1), N, N-bis (1H-pyrazolyl-1-methyl)-p-methoxyaniline (L2), N, N-bis (1H- pyrazolyl-1-methyl)-p-fluoroaniline (L3) and N, N-bis (3, 5-dimethyl-1H-pyrazolyl-1-methyl) aniline (L4), in ethanol yields Zn (II) chloride complexes, ie, L1ZnCl2, L2ZnCl2, L3ZnCl2 and L4ZnCl2. X-ray crystallographic analysis revealed that the Zn atoms of all of the ...