Tris (triorganosilyl) phosphites—New ligands controlling catalytic activity of Pt (0) complex in curing of silicone rubber

I Kownacki, B Marciniec, K Szubert, M Kubicki…

Index: Kownacki, Ireneusz; Marciniec, Bogdan; Szubert, Karol; Kubicki, Maciej; Jankowska, Magdalena; Steinberger, Helmut; Rubinsztajn, Slawomir Applied Catalysis A: General, 2010 , vol. 380, # 1-2 p. 105 - 112

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Citation Number: 8

Abstract

Applying novel and efficient method, new tris (triorganosilyl) phosphites were synthesized and further used for the preparation of new well-defined platinum complexes [Pt (DVTMDS){P (OSiR3) 3}](DVTMDS=(H2CCHSiMe2) 2O, R3= Si7O9 (iOct) 7, iPr3, MePh2, Ph3,(OtBu) 3,(OSiMe3) 3) which were well characterized by spectroscopic methods. Structures of two platinum (0) complexes,[Pt {η4-(H2CCHSiMe2) 2O}{P (OSiPh3) 3}](10) ...