The Journal of Organic Chemistry

Radical Allylations with Trimethyl [2-[(tributylstannyl) methyl]-2-propenyl] silane or Trimethyl [2-[(triphenylstannyl)-methyl]-2-propenyl] silane

DLJ Clive, CC Paul, Z Wang

Index: Clive, Derrick L. J.; Paul, Christine Chua; Wang, Zhongren Journal of Organic Chemistry, 1997 , vol. 62, # 20 p. 7028 - 7032

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Citation Number: 42

Abstract

Radical allylation of the type illustrated in eq 1 (X) halogen) is a well-established and synthetically important reaction. 1-4 Various radical sources, besides alkyl halides, are suitable, 1a, b, d, e, h, k, l, 5 and the reaction can be carried out both by thermal or photochemical procedures. A number of related processes have also been reported in which radical leaving groups other than R3Sn ‚are involved, 5a, b, 6 and much work has ...