Isotope-Labeling Studies Support the Electrophilic Compound I Iron Active Species, FeO3+, for the Carbon–Carbon Bond Cleavage Reaction of the Cholesterol Side- …

FK Yoshimoto, IJ Jung, S Goyal…

Index: Cole, Philip A.; Robinson, Cecil H. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 ,  # 7  p. 2119 - 2125

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Abstract

... Select a Journal or Book. ... tert-Butyldimethylsilyl (TBDMS) chloride was purchased from Oakwood Chemical (Columbia, SC). ... mmol, 1.0 mol equiv) in THF (15 mL) was added at −78 °C, and the reaction was stirred for 1 h. The reaction was quenched with the addition of H 2 O ...