e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Tetrahedron letters
Reactions of 3-alkyl-and 3, 3-dialkyl-1-bromoallenes with organocuprates: Effects of the nature of the cuprate reagent on the regio-and stereoselectivity
AM Caporusso, C Polizzi, L Lardicci
Index: Caporusso, Anna Maria; Polizzi, Carmela; Lardicci, Luciano Tetrahedron Letters, 1987 , vol. 28, # 48 p. 6073 - 6076
Abstract Organocuprates induce 1, 3-and direct substitution in 3-alkyl-and 3, 3-dialkyl-1- bromo-1, 2-dienes leading respectively to either terminal acetylenes or allenic hydrocarbons. The nature of the cuprate exerts a prominent role in determining both the regio-and the stereochemistry of these reactions.
