Synthesis and Spectroscopic Characterization of 1??13C??and 4??13C??Plastoquinone??9

…, HNS van der Haas, M Rossum??Baan…

Index: Boers, Rutger B.; Randulfe, Yolanda Pazos; Van Der Haas, Hendrikus N. S.; Van Rossum-Baan, Marleen; Lugtenburg, Johan European Journal of Organic Chemistry, 2002 ,  # 13  p. 2094 - 2108

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Citation Number: 20

Abstract

Abstract This paper presents the synthesis of 1-13 C-and 4-13 C-plastoquinone-9 and their characterization with NMR spectroscopy and mass spectrometry. The synthetic scheme has been further adapted to introduce 13 C-labeled plastoquinones on all individual and on each combination of positions in the quinone ring. Also a two-step scheme is disclosed to prepare unlabeled plastoquinone-9.(© Wiley-VCH Verlag GmbH, 69451 Weinheim, ...