Tetrahedron letters

Regio-and stereoselective copper-induced isomerization of 2-alkenyl 2-lithiophenyl ethers to 2-(2-alkenyl) phenols

J Barluenga, R Sanz, FJ Fañanás

Index: Barluenga, Jose; Sanz, Roberto; Fananas, Francisco J. Tetrahedron Letters, 1997 , vol. 38, # 34 p. 6103 - 6106

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Citation Number: 16

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... N-Allyl-N-(2-lithioallyl)aniline undergoes intramolecular carbometallation via 5-exo addition on treatment with CuCN, 2-Alkenyl 2-bromophenyl ethers rearrange to 2-(2-alkenyl)phenols by bromine-lithium exchange and further transmetallation with CuCN.