The Journal of Organic Chemistry

Electronic Effects on the Stereochemistry of the Diels—Alder Reaction1

F Kaplan, H Conroy

Index: Kaplan,F.; Conroy,H. Journal of Organic Chemistry, 1963 , vol. 28, p. 1593 - 1596

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Citation Number: 18

Abstract

The Diels-Alder reaction, in which there is the possibility of the formation of more than one product, has been extensively investigated; however, the asymmetrical nature of reacting species has not permitted unequivocal evaluation of the electronic effect in determining the isomer formed. 3 The introduction of a group on the 2-position of the anthracene nucleus permits the formation of two isomeric products in the reaction with maleic anhydride. The ...