The oxidation of (+)-3-carene and the related compounds with t-butyl chromate

T Suga, T Shishibori, T Matsuura

Index: Suga,T. et al. Bulletin of the Chemical Society of Japan, 1972 , vol. 45, p. 1873 - 1876

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Citation Number: 3

Abstract

The oxidation of (+)-3-carene with t-butyl chromate was found to afford 3, α-dimethylstyrene (2), eucarvone (3), 1, 1, 4-trimethylcyclohepta-2, 4-dien-6-one (4), 3-methylacetophenone (5), 8-hydroxy-m-cymene (6), car-3-en-2-one (7),(−)-car-3-en-5-one (8), and (−)-car-3-ene-2, 5-dione (9). The aromatized compound (6) was a major product in the oxidation in an acidic medium, whereas the oxidation in the neutral and the basic media gave the enedione (9) ...