Formation and thermal decomposition of adducts of phthalimidonitrene with spiro (1-pyrazolinecyclopropanes)

…, IV Kostyuchenko, EV Shulishov, BB Averkiev…

Index: Tomilov; Kostyuchenko; Shulishov; Averkiev; Antipin; Nefedov Russian Chemical Bulletin, 1999 , vol. 48, # 7 p. 1316 - 1322

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Abstract

Abstract Oxidation of N-aminophthalimide with lead tetraacetate in the presence of spiro (1- pyrazolinecyclopropanes) at temperature from− 20° C to− 30° C resulted in the formal generation of phthalimidonitrene followed by its addition at the N= N bond of the pyrazoline ring to form 5 (3)-substituted N-{spiro [1-pyrazolinio-3 (5), 1′-cyclopropane]}-N- phthalimidoamides (azimines), whose regioisomeric compositions were determined to a ...