The Journal of Organic Chemistry

Diels-Alder reactions of 2-alkynoyl chlorides with cyclopentadiene: a reinvestigation

E Bäuml, H Mayr

Index: Baeuml, Englbert; Mayr, Herbert Journal of Organic Chemistry, 1983 , vol. 48, # 15 p. 2600 - 2601

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Citation Number: 7

Abstract

(22) Moore, JW; Pearson, RG“Kinetics and Mechanism”, 3rd ed.; Wiley: New York, 1981; p 290 ff.(23) It must be noted that this is a crude calculation; the relations used are exactly true only for two consecutive frat-order reactions. The system we observed involved two parallel pseudo-first-order reactions, followed by a third, consecutive pseudo-first-order reaction. There is no simple kinetic solution which can analyze completely such a system. ...