Charge transfer through cross-hyperconjugated versus cross-π-conjugated bridges: an intervalence charge transfer study

E Göransson, R Emanuelsson, K Jorner, TF Markle…

Index: Goeransson, Erik; Emanuelsson, Rikard; Jorner, Kjell; Markle, Todd F.; Hammarstroem, Leif; Ottosson, Henrik Chemical Science, 2013 , vol. 4, # 9 p. 3522 - 3532

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Citation Number: 17

Abstract

Recently there has been much interest in electron transfer and transport through cross- conjugated molecules as interesting test cases for the interplay between molecular and electronic structure as well as potential motifs in the design of new compounds for molecular electronics. Herein we expand on this concept and present the synthesis and characterization of a series of four organic mixed-valence dyads to probe the effect of the ...