Radical Mechanism in the Elimination of 2-Arylsulfinyl Esters

…, S Rodríguez, J Izquierdo, FV González…

Index: Latorre, Antonio; Lopez, Irakusne; Ramirez, Victoria; Rodriguez, Santiago; Izquierdo, Javier; Gonzalez, Florenci V.; Vicent, Cristian Journal of Organic Chemistry, 2012 , vol. 77, # 11 p. 5191 - 5197

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Citation Number: 6

Abstract

The mechanism of the dehydrosulfenylation of 2-arylsulfinyl esters was investigated. The reaction was found to follow a homolytic cleavage mechanism as verified by electrospray ionization tandem mass spectrometry and experimental work. Rearranged sulfoxides are obtained as byproduct during the elimination reaction.

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