Kinetics and product study of the self-reactions of allyl and allyl peroxy radicals at 296 K

…, TP Murrells, SJ Shalliker, GD Hayman

Index: Jenkin, Michael E.; Murrells, Timothy P.; Shalliker, Stephen J.; Hayman, Garry D. Journal of the Chemical Society, Faraday Transactions, 1993 , vol. 89, # 3 p. 433 - 446

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Citation Number: 93

Abstract

The laser flash photolysis technique, coupled with UV absorption spectroscopy, has been used to investigate the UV spectra and kinetics of reactions of the allyl radical (CH2CHCH2) and the allyl peroxy radical (CH2CHCH2O2) at 296 K and total pressures near atmospheric. CH2CHCH2 radicals were generated by the 193 nm photolysis of hexa-1, 5-diene–N2 mixtures, or the 248 nm photolysis of allyl iodide–N2 mixtures. The 193 nm photolysis of ...