Bulletin of the Chemical Society of Japan

Hydrolytic Reactions of p-Nitrophenyl Esters in Reversed Micellar Systems

H Fujii, T Kawai, H Nishikawa

Index: Fujii,H. et al. Bulletin of the Chemical Society of Japan, 1979 , vol. 52, p. 1978 - 1982

Full Text: HTML

Citation Number: 11

Abstract

Hydrolytic reactions of several p-nitrophenyl esters were studied with and without catalysts in reversed micellar systems consisting of sodium octanoate, 1-hexanol and water. Hydrolytic rate constants become very large as compared with those in aqueous solutions, increasing with decrease in the molar ratio of water to sodium octanoate (R-value). The results of kinetic measurements were discussed in terms of the behavior of water ...