Allyl amides were synthesised from the reaction of allyl alcohols and halogenated nitriles using a platinum multifaceted catalysis approach in which both the nucleophilic addition and subsequent [3, 3]-sigmatropic rearrangement steps of the process were catalysed by the same complex. Additionally, 1 H/13 C {1 H} NMR and GC studies provided the first insights into the mechanism of this transformation.
