Synthesis, molecular structure, and NMR spectra of trimesitylaluminum, a novel molecule with three coordinate aluminum

JJ Jerius, JM Hahn, AFMM Rahman, O Mols…

Index: Jerius, John J.; Hahn, Juliet M.; Rahman, A. F. M. Maqsudur; Mols, Ole; Ilsley, William H.; Oliver, John P. Organometallics, 1986 , vol. 5, p. 1812 - 1814

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Citation Number: 51

Abstract

All simple organoaluminum compounds which have been characterized by single-crystal X- ray diffraction methods have been shown to be dimeric in the solid state with three-centered, two-electron carbon bridge bonds2 or have chain structures as exhibited by Me2AICp3 and Al-(CH2Ph) 3.4 The only monomeric structure described in detail is that of AIMe, monomer determined in the gas phase by electron diffraction5 In solution the majority of these ...