Acta Phys Chim Sin

Kinetics of Acid-Catalyzed Smiles Rearrangement of 2, 6-Dimethoxy-2-pyrimidinyloxy-N-arylbenzylamine Derivatives

PZ ZHANG, MJ YE, WL HU, J WU

Index: Mi, Xia; Huang, Mengmeng; Feng, Yujian; Wu, Yangjie Synlett, 2012 , vol. 23, # 8 p. 1257 - 1261

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Abstract

The kinetics of the acid-catalyzed Smiles rearrangement reactions of 2, 6-dimethoxy-2- pyrimidinyloxy-N-arylbenzylamine derivatives was investigated. The effects of initial concentrations of hydrochloric acid, solvent, temperature, and substituent on reaction rates