The Journal of Organic Chemistry

. alpha.-Metalated tertiary enol carbamates. New acyl anion equivalents

S Sengupta, V Snieckus

Index: Sengupta, Saumitra; Snieckus, Victor Journal of Organic Chemistry, 1990 , vol. 55, # 22 p. 5680 - 5683

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Citation Number: 63

Abstract

Summary: a-Metalated enol carbamate lg constitutes a new, conveniently generated (sec- BuLi/TMEDA/THF/-78 OC), and well-behaved acyl anion equivalent. The utility and scope of this synthon for the preparation of a variety of useful synthetic building blocks (4, 6, 8, 11, 12) has been demonstrated.

~85%

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