Synthetic Communications

Synthesis of Dienals by Condensation of Carbonyl Compounds with a New Reagent, the 4-Lithio-1-trimethylsiloxybutadiene

B Contreras, L Duhamel, G Ple

Index: Contreras, Beatriz; Duhamel, Lucette; Ple, Gerard Synthetic Communications, 1990 , vol. 20, # 19 p. 2983 - 2990

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Citation Number: 22

Abstract

Laboratoire de Chimie Organique, Unid de recherche AssociCe au CNRS no 464, Universid de Rouen, BP 68, 76134 MONT SAINT AIGNAN CEDEX, France. ... Abstract : Carbonyl compounds 2 are converted into conjugated dienals ,L in a one pot reaction, by a condensation with Iithio-4 trimethylsiloxybutadiene, followed by a mild acidic hydrolysis. ... Polyethylenic aldehydes are very useful building blocks in organic synthesis. In particular, they can been used for ...