Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Solvolytic hydroperoxide rearrangements IV. Selective rearrangement of spiro[5,2]octan-4-ol . ... Rearrangement of spiro[5,2]octan-4-ol, 1, in acidified THF-H 2 O 2 is a selective process in which substitution occurs with retention of configuration and ring-expansion with ...