Tetrahedron

Carbon–carbon bond construction on solid support: triethylborane-induced radical reactions of oxime ethers

H Miyabe, A Nishimura, Y Fujishima, T Naito

Index: Miyabe, Hideto; Nishimura, Azusa; Fujishima, Yumi; Naito, Takeaki Tetrahedron, 2003 , vol. 59, # 11 p. 1901 - 1907

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Citation Number: 36

Abstract

The triethylborane-induced solid-phase radical reaction was studied. The solid-phase radical reaction of oxime ether anchored to Wang resin proceeded smoothly to give the α- amino acid derivatives. The carbon–carbon bond-forming radical reaction of TentaGel OH resin-bound glyoxylic oxime ether proceeded even in aqueous media.