Organometallics

Amination of Aryl Iodides Catalyzed by a Palladium–Copper Complex Supported by a Chelate-Bridging Ligand

N Tsukada, N Ohnishi, S Aono, F Takahashi

Index: Tsukada, Naofumi; Ohnishi, Nozomi; Aono, Shiori; Takahashi, Fusako Organometallics, 2012 , vol. 31, # 21 p. 7336 - 7338

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Citation Number: 7

Abstract

Both palladium and copper complexes are widely used as catalysts in various transformations of organic compounds. Although each of these two metals works alone in most reactions, these metals also cooperate in some important catalysis to enable transformations difficult for a single metal. For example, copper serves as a reoxidizing agent of palladium in the Wacker oxidation(1) and activates a terminal alkyne and delivers it to palladium in the ...