Novel heterocyclic anions: benzo [b] thiophene dianion, the first sulphur doubly charged 4 n π system

Y Cohen, J Klein, M Rabinovitz

Index: Cohen, Yoram; Klein, Joseph; Rabinovitz, Mordecai Journal of the Chemical Society, Chemical Communications, 1985 , # 15 p. 1033 - 1034

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Abstract

Extensive theoretical and experimental studies have been performed on charged n-conjugated polybenzenoid systems in the last two decades.1J The scarcity of information on heterocyclic doubly charged species3 as well as the limited success in the preparation of nitrogen polyheterocyclic dian- ions4 prompted us to undertake the investigation of a sulphur-containing polycyclic dianion. In view of the weak- ness of the carbon-sulphur? bond, the preparation of such ...