Palladium-Catalyzed Procedures for [3 + 21 Annulation via Intramolecular Alkenylpalladation and Arylpalladation' Summary: Treatment of dienolates derived from cyclo- hexenes activated by carbonyl groups with y-iodoallyl electrophiles 1 and o-iodobenzyl electrophiles 2 followed by cyclization catalyzed by Pd complexes, eg, Pd(PPhs)r, ... (1) Metal-Promoted Cyclization. 21. Part 20 O'Connor, B.; Zhang, Y.; Negishi, E.; Luo, FT; Cheng, JW TetrahedronLett. ...