Preparation, structural characterization, and photochemical reactions of silyl-and germylborates

M Nanjo, K Matsudo, M Kurihara, S Nakamura…

Index: Nanjo, Masato; Matsudo, Kazuhiko; Kurihara, Mari; Nakamura, Sayaka; Sakaguchi, Yoshio; Hayashi, Hisaharu; Mochida, Kunio Organometallics, 2006 , vol. 25, # 4 p. 832 - 838

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Citation Number: 11

Abstract

Silylborates (Li [Ph n Me3-n SiBPh3], n= 1-3) and germylborates (Li [Ph n Me3-n GeBPh3], n= 1-3; M [Et3GeBPh3], M= Li, Na, K) were prepared by the reaction of the corresponding silyl-and germylalkali metals with triphenylborane, and their structures were established by spectroscopic methods and X-ray crystallography. The photochemical reactions of silyl-and germylborates were investigated by chemical trapping experiments and the CIDEP ...