Reactions of 1, 1-diarylethylenes and 1, 1-diarylimines with CF3OF

TB Patrick, GL Cantrell, SM Inga

Index: Patrick, Timothy B.; Cantrell, Gary L.; Inga, Sandra M. Journal of Organic Chemistry, 1980 , vol. 45, # 8 p. 1409 - 1413

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Citation Number: 33

Abstract

1, l-Diphenylethylene (1) reacts with CF, OF to give products 2-6 in a cationic process. 9- Ethylidenefluorene reacts with CF30F to yield 8 and 10. Amitriptyline (12) furnished a difluoro adduct (13) in low yield. Benzophenone oxime (14) gave a Beckmann rearrangement product on reaction with CF30F. Fluorenone ani1 (15) produced mainly fluorenone from reaction with CF30F. Diazepam (16) gave a 1: l adduct (18) with CF30F. ...