Abstract: Irradiation of matrix-isolated dimethyldiazidosilane yields dimethylsilylene (1) as the major product. Photoselection on the 450-nm absorption band of 1 with polarized 488- nm light, which converts 1 into 1-methylsilene (2), permitted the assignment of six IR transitions of 1 and twelve IR transitions of 2 as in-plane or out-of-plane polarized. Photoselection on the 260-nm absorption band of 2 with polarized 248-nm light, which ...
![(5Z)-2-amino-5-[[4-(2-phenoxyethoxy)phenyl]methylidene]-1,3-thiazol-4-one Structure](https://image.chemsrc.com/caspic/319/6376-86-9.png)
