e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Decomposition of 1, 3-dialkyltriazenes in aqueous buffers: Kinetic and mechanistic studies
RH Smith, CL Denlinger, R Kupper…
Index: Smith, Richard H.; Denlinger, Cheryl L.; Kupper, Robert; Mehl, Andrew F.; Michejda, Christopher J. Journal of the American Chemical Society, 1986 , vol. 108, # 13 p. 3726 - 3730
Abstract: 1, 3-Dialkyltriazenes, prepared by the reaction of alkyl azides with alkyllithiums, are stable as pure liquids or in aprotic solutions. The kinetics of decomposition of 1, 3- dimethyltriazene (DMT) were investigated in buffered, aqueous solutions over the pH range of 9-12. The reaction is acid-catalyzed since the rate is inversely proportional to pH. The invariance of the rate with (cyclohexy1amino) propanesulfonic acid (CAPS) buffer ...
