Chinese Journal of Chemistry

Synthesis, Characterization and Ethylene Oligomerization Behavior of Neutral Nickel Complexes Bearing N??Fluorinated Phenyl Salicylaldiminato Chelate Ligands

L Song, S Song, J Huang

Index: Song, Liping; Song, Shaodi; Huang, Jiling Chinese Journal of Chemistry, 2012 , vol. 30, # 5 p. 1119 - 1126

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Abstract

Abstract A series of neutral nickel complexes featuring N-fluorinated phenyl salicylaldiminato chelate ligands was synthesized, and the novel molecular structure of complex C14 was further confirmed by X-ray crystallographic analysis. The neutral nickel complexes showed high activity up to 9.96× 10 5 g oligomers/(mol Ni· h) and high selectivity of C 6 in catalyzing ethylene oligomerization using methylaluminoxane (MAO) as ...