One-dimensional luminescent nanoaggregates of perylene bisimides

…, Z Chen, V Dehm, V Stepanenko

Index: Wuerthner, Frank; Chen, Zhijian; Dehm, Volker; Stepanenko, Vladimir Chemical Communications, 2006 , # 11 p. 1188 - 1190

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Citation Number: 85

Abstract

Here we present a new, highly photoluminescent PTCDI derivative 4 (Φ f = 0.65 in methylcyclohexane (MCH)) which self-assembles into well defined one-dimensional columnar stacks that exhibit similar spectacular optical features to those reported by Forrest and co-workers for archetype organic crystals of PTCDA. 6 As shown in Scheme 1, perylene bisimide 4 was synthesized by imidization of PTCDA with tridodecylaniline 3 using Zn(OAc) 2 as catalyst. Aniline ...