Ferrocence-based phosphine–triazine ligands for highly efficient Suzuki–Miyaura cross-coupling reaction of aryl chlorides

…, J Deng, JD Huang, DY Wang, ZC Duan, Z Zheng

Index: Yu, Sai-Bo; Hu, Xiang-Ping; Deng, Jun; Huang, Jia-Di; Wang, Dao-Yong; Duan, Zheng-Chao; Zheng, Zhuo Tetrahedron Letters, 2008 , vol. 49, # 7 p. 1253 - 1256

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Citation Number: 14

Abstract

A series of ferrocene-based phosphine–triazine ligands were successfully employed in the Pd-catalyzed Suzuki–Miyaura cross-coupling reaction of aryl chlorides with arylboronic acids, with ligand 1b was demonstrated to be the most effective one. Under optimized reaction conditions, the catalytic system displayed a remarkable tolerance towards electron- donating substituents and electron-withdrawing substituents.