Variable coordination behaviour of pyrazole-containing N, P and N, P (O) ligands towards palladium (II)

…, NJ Long, PW Miller, AJP White, PB Hitchcock…

Index: Kealey, Steven; Long, Nicholas J.; Miller, Philip W.; White, Andrew J. P.; Hitchcock, Peter B.; Gee, Antony Dalton Transactions, 2007 , # 26 p. 2823 - 2832

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Citation Number: 14

Abstract

Three bidentate, mixed-donor ligands based on a triphenylphosphine unit bearing a pyrazole group in the ortho-position of one phenyl ring have been synthesised; the N, P ligand [2-(3-pyrazolyl) phenyl] diphenylphosphine pzphos has been synthesised and transformed into new N, P (O) and N, P (S) derivatives,[2-(3-pyrazolyl) phenyl] diphenylphosphine oxide pzphos (O) and [2-(3-pyrazolyl) phenyl] diphenylphosphine ...