Solvent and substituent effects on rearrangement of 4-(4-X-phenyl)-2, 7-dioxa-3-azabicyclo [3, 3, 0] oct-3-enes

L Fišera, M Konopíková, L Štibrányi…

Index: Fisera, Lubor; Konopikova, Marta; Stibranyi, Ladislav; Timpe, Hans-Joachim Collection of Czechoslovak Chemical Communications, 1985 , vol. 50, # 9 p. 1971 - 1981

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Citation Number: 9

Abstract

Abstract Preparation of the title compounds V is described. They give, on irradiation, the 2, 3- dihydro-6H-1, 3-oxazine derivatives VI as the main products besides the tetrahydrofuro [3, 4- d] oxazoline derivatives VII. The VI to VII product ratio depends on the substituent bound to the aromatic residue. Polar solvents favour formation of the VI derivatives in the order Cl> H> CH 3. In non-polar solvents the proportion of VII is increased. The quantum yields of the ...