Synthesis, crystal structure and optoelectronic properties of a new unsymmetrical photochromic diarylethene

T Yang, S Pu, C Fan, G Liu

Index: Yang, Tianshe; Pu, Shouzhi; Fan, Congbin; Liu, Gang Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2008 , vol. 70, # 5 p. 1065 - 1072

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Citation Number: 16

Abstract

A new unsymmetrical photochromic diarylethene, 1-(2-methyl-5-phenyl-3-thienyl)-2-[2- methyl-5-(3-trifluoromethylphenyl)-3-thienyl] perfluorocyclopentene (1a), was synthesized and its structure was determined by single-crystal X-ray diffraction analysis. Its optical and electrochemical properties, including photochromic reactivity both in solution and in the solid state (PMMA film and the single-crystalline phase), fluorescence and electrochemical ...