The 3, 3-dimethyl-2-azabicyclo [2.2. 2] octyl system as a Bredt's rule kinetically stabilized dialkylamino group in electron-transfer studies

SF Nelsen, PM Gannett

Index: Nelsen,S.F.; Gannett,P.M. Journal of the American Chemical Society, 1982 , vol. 104, p. 5292

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Citation Number: 14

Abstract

Abstract: PE and CV data are reported for electron removal from 2-substituted 3, 3-dimethyl- 2-azabicyclo [2.2. 2] octyl (2-ADO) derivatives in which the substituent is chloro, dimethylamino, 2-ADO, and-N= N-2-ADO and compared with that for their 9-azabicyclo [3.3. l] nonyl (9-ABN) analogues. The differences observed in both IP, and Eo'in the two series of compounds are dominated by their steric differences; 2-ADO has tert, sec-alkyl ...