Fischer Indolizations as a Strategic Platform for the Total Synthesis of Picrinine

JM Smith, J Moreno, BW Boal…

Index: Battersby, Alan R.; Thompson, Mervyn; Gluesenkamp, Karl-Heinz; Tietze, Lutz-F. Chemische Berichte, 1981 , vol. 114, # 10 p. 3430 - 3438

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Citation Number: 13

Abstract

... Volume: Page ... Figure 4. Summary of total synthesis of aspidophylline A (10) and initial synthetic plan for picrinine (1) utilizing the key ... 3). Reduction of the enoate, followed by acid-promoted cleavage of the dimethyl ketal with pyridinium p-toluenesulfonate (PPTS ...