Helvetica Chimica Acta

Sur l'hydrolyse acide du méthoxy??1??hexène??1??yne??3 et du méthoxy??1??hexadiène??1, 3. Synthèse de pyrazoles substitués et du cis??hexène??3??al

M Winter

Index: Winter,M. Helvetica Chimica Acta, 1963 , vol. 46, p. 1754 - 1760

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Citation Number: 6

Abstract

Abstract Acid hydrolysis of 1-methoxy-1-hexene-3-yne (I) gives as main product the unstable β-oxohexanal, and not β-hexynal as suggested earlier by Herbertz. The mechanism of this reaction is briefly discussed. Acid hydrolysis of I in the presence of phenylhydrazine yields ...