Smectic liquid crystals with 'de Vries-like'properties are characterized by a maximum layer contraction of≤ 1% upon transition from the orthogonal SmA phase to the tilted SmC phase. We show that binary mixtures of 'de Vries-like'and conventional SmC mesogens with a molecular length ratio of 1.34 undergo a SmA–SmC phase transition with a maximum layer contraction ranging from 1.0 to 1.9% depending on the mixture composition.
