Conversion of some substituted phenols to the corresponding masked thiophenols, synthesis of a dinickel (II) dithiolate macrocyclic complex and isolation of some …

…, GB Caygill, PD Croucher, TC Davidson…

Index: Brooker, Sally; Caygill, Graham B.; Croucher, Paul D.; Davidson, Tony C.; Clive, Derrick L. J.; Magnuson, Stephen R.; Cramer, Stephen P.; Ralston, Corie Y. Journal of the Chemical Society, Dalton Transactions, 2000 , # 18 p. 3113 - 3121

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Citation Number: 23

Abstract

A modified preparation of the masked thiolate head unit S-(2, 6-diformyl-4-methylphenyl) dimethylthiocarbamate 6 is detailed and two new masked thiolate head units, S-(2, 6- diformyl-4-tert-butylphenyl) dimethylthiocarbamate 7 and S-(2-formylphenyl) dimethylthiocarbamate 8, are prepared by this method. The synthesis, crystal structure, NMR spectra and electrochemical properties of the first macrocyclic complex to be derived from ...